Handbook of Maleic Anhydride Based Materials by Osama M. Musa

Author:Osama M. Musa
Language: eng
Format: epub
Publisher: Springer International Publishing, Cham

Side reactions can occur that inactivate the catalyst system. For example, cross-metathesis side reactions not only broaden the molecular weight distribution during the polymerization, analogous to chain transfer in classical systems (see Scheme 6.4), but can also lead to the formation of catalyst dimers that are no longer active (see Scheme 6.3b).

Scheme 6.4Cross-metathesis side reactions during ROMP and storage (Adapted from Sutthasupa, S.; Shiotsuki, M., Sanda, F., Polymer Journal, 2010, 42, p 905. Copyright 2010 with permission from Nature Publishing Group)

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